The world’s most expensive player was messing around with fellow Paris Saint-Germain star Dani Alves when he unleashed a wicked right-footed shot in the close confines of the changing room.
The group had been playing an epic game of headers and volleys over a table.
But Neymar put a stop to it all after being set up by Alves - and look at Marcelo flinch as the ball whizzes past him.
Brazil host Ecuador on Friday in the first of two World Cup qualifiers this month.
And Neymar goes into it in fine form given his electric start for PSG following his arrival from Barcelona.
Colombia then welcome manager Tite's side on September 5.
Wantaway Liverpool star Philippe Coutinho has been declared fit for Brazil - despite not playing for Jurgen Klopp due to a "back injury".
Liverpool have turned down a £118million bid for the forward -
but recent reports claim a £148m transfer has been agreed .
However there is a delay in it being finalised because Klopp wants to find the necessary replacements. with little over a day to do so.
Klopp did sign Naby Keita from RB Leipzig for a club-record £48m but he will not arrive until next summer.
And the Kop side remain firm in their stand over Coutinho leaving.
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